Nanocrystalline Silicon Carrier Collectors for Silicon Heterojunction Solar Cells and Impact on Low-Temperature Device Characteristics

作者：Nogay Gizem^*; Seif Johannes Peter; Riesen Yannick; Tomasi Andrea; Jeangros Quentin; Wyrsch Nicolas; Haug Franz Josef; De Wolf Stefaan; Ballif Christophe

来源：IEEE Journal of Photovoltaics, 2016, 6(6): 1654-1662.

DOI：10.1109/JPHOTOV.2016.2604574

• Carrier transport
• contact resistivity
• nanocrystalline silicon
• Schottky barrier
• silicon heterojunction (SHJ)
• solar cells
• temperature dependence

Silicon heterojunction solar cells typically use stacks of hydrogenated intrinsic/doped amorphous silicon layers as carrier selective contacts. However, the use of these layers may cause parasitic optical absorption losses and moderate fill factor (FF) values due to a high contact resistivity. In this study, we show that the replacement of doped amorphous silicon with nanocrystalline silicon is beneficial for device performance. Optically, we observe an improved short-circuit current density when these layers are applied to the front side of the device. Electrically, we observe a lower contact resistivity, as well as higher FF. Importantly, our cell parameter analysis, performed in a temperature range from -100 to +80 degrees C, reveals that the use of hole-collecting p-type nanocrystalline layer suppresses the carrier transport barrier, maintaining FFs in the range of 70% at -100 degrees C, whereas it drops to 40% for standard amorphous doped layers. The same analysis also reveals a saturation onset of the open-circuit voltage at -100 degrees C using doped nanocrystalline layers, compared with saturation onset at -60 degrees C for doped amorphous layers. These findings hint at a reduced importance of the parasitic Schottky barrier at the interface between the transparent electrodes and the selective contact in the case of nanocrystalline layer implementation.

• 出版日期2016-11