Amination of electron deficient aryl chlorides promoted by nano sized Mg(OH)(2) under transition metals free condition

作者：Cui, Zhi Hao; Meng, Zi Hui; Mi, Yan Qing; Wang, Peng; Wang, Qi; Zhao, Lin Man; Cui, Ke Jian; Yu, Fang; Xu, Zhi Bin^*

来源：Chinese Chemical Letters, 2012, 23(2): 137-140.

DOI：10.1016/j.cclet.2011.11.009

• Amination
• Electron deficient aryl chloride
• Cyclic secondary amines
• Nano sized
• Magnesium hydroxide

This paper presents the amination reactions of electron deficient aryl chlorides promoted by Mg(OH)(2) without transition metals. Only using stoichiometric amount of nano sized Mg(OH)(2), good to moderate isolated yields could be achieved in N-methylpyrrolidone (NMP) after 24 h at 150 degrees C.

• 出版日期2012-2
• 单位北京理工大学