科研之友
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摘要
Nucleophilic racemic amines have been synthesized utilizing a C(7n)C(5x) free-radical cascade reaction from a bis-allyl amine starting material. Being potentially useful organocatalytic bases as is evident from their screening in the Baylis-Hillman reaction, optically pure amines were also synthesized from optically pure aldehydes (-) or (+)-4. Bis-allyl amides under similar radical reaction condition resulted in C(7n) cyclized products.
- 出版日期2008-10-13
