Oxidation of alcohols using iodosylbenzene as oxidant catalyzed by ruthenium complexes under mild reaction conditions

作者：Yang Zhi Wang; Kang Qiao Xiang; Quan Feng; Lei Zi Qiang^*

来源：Journal of Molecular Catalysis A: Chemical , 2007, 261(2): 190-195.

DOI：10.1016/j.molcata.2006.07.051

• alcohols
• catalytic oxidation
• ruthenium complexes
• iodosylbenzene

Aromatic and alkyl alcohols were oxidized to the corresponding aldehydes or ketones at room temperature with high conversion and selectivity to the desired products of 100% using iodosylbenzene as oxidant catalyzed by ruthenium complexes Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin, Quin-Ru-Quin and Bipy-Ru-Quin (where Phen = 1, 10-phenanthroline, Quin = 8-hydroxyquinoline, Bipy = 2,2'-bipyridine). The reaction conditions are mild, the ligands used in this oxidation system are commercially available and the procedure for the preparation of the complexes is very simple.

• 出版日期2007-1-18
• 单位西北师范大学