A sixfold interpenetrated microporous MOF constructed from heterometallic tetranuclear cluster exhibiting selective gas adsorption

作者：Li, Yun-Wu; Wang, Li-Fu; He, Kun-Huan; Chen, Qiang; Bu, Xian-He^*

来源：Dalton Transactions, 2011, 40(40): 10319-10321.

DOI：10.1039/c1dt10554j

• METAL-ORGANIC FRAMEWORK
• COORDINATION POLYMER
• SORPTION PROPERTIES
• OPEN CHANNELS
• MOLECULES
• STABILITY
• NETWORKS
• TOPOLOGY
• HYDROGEN
• LIGANDS

A sixfold interpenetrated microporous MOF has been constructed from a heterometallic tetranuclear cluster. The framework contains two types of 1D micro-channels along different directions. Moreover, this compound exhibits high selective gas sorption for H-2 over N-2.

• 出版日期2011
• 单位南开大学