A sol-gel route for the development of rare-earth aluminum borate nanopowders and transparent thin films

作者：Maia Lauro J Q^*; Mastelaro Valmor R; Pairis Sebastien; Hernandes Antonio C; Ibanez Alain

来源：Journal of Solid State Chemistry, 2007, 180(2): 611-618.

DOI：10.1016/j.jssc.2006.11.016

• sol-gel
• propionic acid
• Y0.9Er0.1Al3(BO3)(4)
• nanopowders
• thin films
• thermal analyses
• XRD
• SEM
• FEG

A new sol-gel route was applied to obtain Y0.9Er0.1Al3(BO3)(4) crystalline powders and amorphous thin films by using Al(acac)(3), B(OPri)(3), Y(NO3)(3) center dot 6H(2)O, and Er(NO3)(3) center dot 5H(2)O as starting materials dissolved in propionic acid and ethyl alcohol mixtures. Our study shows that propionic acid acts as good chelant agent for yttrium and erbium ions while ethyl alcohol allows to dissolve Al(acac)(3). This process makes the resulting sols very stable to obtain homogeneous gels and transparent amorphous thin films. In addition, the propionic acid prevents the sol precipitation, making easy porous- and crack-free thin film depositions. Chemical reactions involved in the complexation were discussed. As-prepared powders and films are amorphous and present a good thermal stability due to their high glass transition (746 degrees C) and crystallization temperatures (830 degrees C). This new sol-get route showed to be adequate to obtain dense and crack-free thin films free of organic and hydroxyl groups that can be considered as promising materials to be used in integrated optical systems.

• 出版日期2007-2