Unprecedented High Local Charge-carrier Mobility in P3HT Revealed by Direct and Alternating Current Methods

作者:Yasutani Yoshihiro; Saeki Akinori*; Fukumatsu Takahiro; Koizumi Yoshiko; Seki Shu
来源:Chemistry Letters, 2013, 42(1): 19-21.
DOI:10.1246/cl.2013.19

摘要

The impacts of solvent and thermal annealing on the mobility and photogeneration efficiency of free charge carriers in regioregular poly(3-hexylthiophene) were investigated by flash-photolysis time-resolved microwave conductivity measurements, transient absorption spectroscopy of the perylenediimide radical anion, and photocurrent measurements of a comb-type interdigitated electrode. A respectable high mobility of 0.62 cm(2)V(-1) s(-1) was found as a three-dimensional value, highlighting the unprecedented electronic nature of the conjugated polymer.

  • 出版日期2013-1-5