A solution strategy for the film model for non-isothermal gas-liquid reactions

作者：Limtrakul Sunun^*; Kongto Abhijart; Vatanatham Terdthai; Ramachandran Palghat A

来源：Chemical Engineering Science, 2010, 65(15): 4420-4431.

DOI：10.1016/j.ces.2010.04.008

• Gas-liquid reaction
• Absorption with chemical reaction
• Film theory
• Boundary element method
• Heat transfer
• Mass Transfer
• Numerical analysis
• Modeling of chemical reactors

A general solution strategy for the film model for gas-liquid reaction has been proposed using the boundary element method (BEM) of discretization over subinterval sing as-liquid films. Non-isothermal effects in the film are included and the associated temperature changes near the gas-liquid interface are computed. The accuracy of the solution procedure is first established using some simple isothermal and non-isothermal bench mark problems and with semi-analytical solutions. Then illustrative results are presented for a non-isothermal series reaction system to illustrate effects of various parameters such as Arrhenius number, solubility changes with temperature, effect of volatility of the liquid phase reactant, etc. The proposed solution method provides fast and accurate values for interfacial fluxes and fluxes into the bulk liquid in addition to concentration profiles. Hence the method is extremely useful for coupling local effects of the film model with global effects based on CFD coupled compartmental model for gas-liquid reactors.

• 出版日期2010-8-1