Superhydrophobicity of hierarchical ZnO nanowire coatings

作者:Gong, Maogang*; Yang, Zhou; Xu, Xiaoliang; Jasion, Daniel; Mou, Shin; Zhang, Hongdi; Long, Yunze; Ren, Shenqiang
来源:Journal of Materials Chemistry A, 2014, 2(17): 6180-6184.
DOI:10.1039/c3ta14102k

摘要

Hierarchical superhydrophobic surfaces were constructed by growing various lengths of ZnO nanowires on micro-scale Si pyramids produced by chemical etching. The nano-size effect on wettability of nano/micro complex structures has been investigated by adjusting the ZnO nanowire length. As the nanowire length on the Si pyramid surface increases, a transition from the Wenzel state to the Cassie state occurs. A water contact angle as high as 169.1 degrees, with a contact angle hysteresis less than 1.3 degrees, was formed by growing ZnO nanowires of a suitable length on Si micro-pyramids. Compression and impact experiments further demonstrate the robust superhydrophobicity of ZnO nanowire-Si pyramid hierarchical structures.