Determination of Polycyclic Aromatic Hydrocarbons in Soil by Miniaturized Ultrasonic Extraction and Gas Chromatography-Mass Selective Detection

作者：Ozcan Senar^*; Tor Ali; Aydin Mehmet Emin

来源：Clean-Soil Air Water, 2009, 37(10): 811-817.

DOI：10.1002/clen.200900110

• Factorial design
• Miniaturized extraction
• Polycyclic aromatic hydrocarbons
• Soil
• Ultrasonic extraction

A miniaturized ultrasonic extraction procedure was developed for the determination of polycyclic aromatic hydrocarbons (PAHs) in soil by gas chromatography-mass spectrometry. After determination of the most suitable extraction solvent with 5 min sonication time, several other parameters (sample amount, solvent volume and number of extraction times) were optimized using a 2(3) factorial experimental design. Recoveries of PAHs from spiked soil samples were over 90% for three different fortification levels between 50 and 300 mu g/kg, and relative standard deviations of the recoveries were in the range of < 1 - 15%. The limits of detection ranged from 0.002 to 1.87 mu g/kg. The performance of the developed procedure was also compared with other traditional Soxhlet, shake flask and large scale ultrasonic extraction procedures on real soil samples, and extraction methods showed comparable efficiencies. The proposed procedure required small volumes of solvent and sample. It was practicable, rapid and easy to use for analysis of PAHs in soils.

• 出版日期2009-10