科研之友
微信
新浪微博
Facebook
分享链接
摘要
We systematically investigate the influence of free-electron concentrations from 1.5x10(17) cm(-3) up to 1.6x10(21) cm(-3) on the optical properties of single-crystalline In2O3 in the cubic bixbyite structure. Dielectric functions of bulk crystals and epitaxial films on various substrates are determined by spectroscopic ellipsometry from the mid-infrared (37 meV approximate to 300 cm(-1)) into the ultraviolet (6.5 eV) spectral region. Eight transverse optical phonon modes are resolvable for low carrier-density material. The analysis of the plasma frequencies yields effective electron masses which increase from a zero-density mass of m* = 0.18m(0) to 0.4m(0) at n = 10(21) cm(-3). This mirrors the nonparabolicity of the conduction band being described by an analytical expression. The onset of absorption due to dipole-allowed interband transitions is found at 3.8 eV for n <= 1019 cm(-3). It undergoes a blue-shift (effective Burstein-Moss shift) for higher electron densities as a result of the dominating phase-space filling compared to band gap renormalization. A comprehensive model describing the absorption onset is developed, taking nonparabolicity into account, yielding an accurate description and explanation of the observations. The agreement of modeled and measured absorption onset independently supports the effective electronmasses derived from infrared data. The high-frequency dielectric constant of undoped In2O3 is found to be epsilon(infinity) = (4.08 +/- 0.02).
- 出版日期2016-1-7
