A chiral [(dipyridylphosphine)RuCl2(1,3-diphenylpropanediamine)] catalyst for the hydrogenation of aromatic ketones

作者：Grasa GA; Zanotti Gerosa A; Hems WP^*

来源：Journal of Organometallic Chemistry, 2006, 691(10): 2332-2334.

DOI：10.1016/j.jorganchem.2005.12.035

• [(diphosphine)RuCl2(diamine)]catalyst
• asymmetric hydrogenation

The use of chiral 1,3-diphenylpropanediamine in combination with Ru-Xyl-P-Phos, gave up to 95% ee in the hydrogenation of acetophenone.

• 出版日期2006-5-1