A [2]rotaxane-based H-1 NMR spectroscopic probe for the simultaneous identification of physiologically important metal ions in solution

作者:Chen Nai Chia; Huang Po Yi; Lai Chien Chen; Liu Yi Hung; Wang Yu; Peng Shie Ming; Chiu Sheng Hsien*
来源:Chemical Communications, 2007, (40): 4122-4124.
DOI:10.1039/b706461f

摘要

We describe a [ 2] rotaxane molecule that exhibits distinct signals in its H-1 NMR spectra upon the complexation of physiologically important Li+, Na+, Mg2+ and Ca2+ ions; thus, the identification of these metal ions in solution is possible from the analysis of a single H-1 NMR spectrum of a single molecular sensor.