A novel LaGa0.65Mg0.15Ni0.20O3-delta perovskite catalyst with high performance for the partial oxidation of methane to syngas

作者：Meng, Bo; Zhang, Hongyu; Zhao, Zihang; Wang, Xiaobin; Jin, Yun^*; Liu, Shaomin

来源：Catalysis Today, 2016, 259: 388-392.

DOI：10.1016/j.cattod.2015.05.009

• Nanostructures
• Oxides
• Sol-gel
• Ceramics

A novel perovskite catalyst with the composition of LaGa0.65Mg0.15Ni0.20O3-delta (LGMN) is synthesized by the sol-gel combustion technique. The nanostructure catalyst has been examined for the partial oxidation of methane (POM) into syngas. A variety of characterizations including XRD, BET, SEM and TG-DTA were applied to determine the crystalline structure of the formed nanosized particles. The syngas selectivity over the catalyst may reach up to 100% with the methane conversions larger than 81% at 900 degrees C and 55 mL min(-1) g(-1) feed velocity. XRD and thermal analysis reveals that the LGMN powder has maintained the perovskite structure very well after 210 h POM reaction signaling its high chemical stability.

• 出版日期2016-1-1
• 单位山东理工大学