Additive- and Photocatalyst-Free Borylation of Arylazo Sulfones under Visible Light

作者：Xu, Yuliang; Yang, Xinying; Fang, Hao^*

来源：Journal of Organic Chemistry, 2018, 83(20): 12831-12837.

DOI：10.1021/acs.joc.8b01662

• METAL-FREE BORYLATION
• ALKOXY DIBORON REAGENTS
• NI-CATALYZED BORYLATION
• CROSS-COUPLING REACTION
• ROOM-TEMPERATURE
• DECARBOXYLATIVE BORYLATION
• SELECTIVE REACTIONS
• ARYLBORONIC ESTERS
• SYNTHETIC ROUTE
• IN-SITU

We developed a photocatalyst-free and additive-free, visible light induced borylation reaction using arylazo sulfones as starting material. This protocol shows some advantages such as mild conditions, simple equipment, and wide substrate scope, which gives a complementary protocol for the preparation of arylboronates.

• 出版日期2018-10-19
• 单位山东大学