A three-dimensional supramolecular complex [Cs(DB24C8)][CuBr2] based on C-H center dot center dot center dot pi and Cs center dot center dot center dot Br weak interactions

作者：Hu Mancheng^*; Wang Xiuhang; Jiang Yucheng; Li Shu'ni

来源：Inorganic Chemistry Communications, 2008, 11(1): 85-88.

DOI：10.1016/j.inoche.2007.10.023

• DB24C8 complex
• C-H center dot center dot center dot pi interaction
• Cs center dot center dot center dot Br interaction
• (4,4) network
• supramolecular structure

A new supramolecular complex [Cs(DB24C8)][CuBr2] (1) (DB24C8 = Dibenzo-24-Crown-8) has been prepared, characterized and structurally investigated. The structure of complex 1 features a two-dimensional (2D) (4,4) network in the ac plane based on C-H center dot center dot center dot pi interactions and the dimensionality is further increased to 3D by Cs center dot center dot center dot Br weak interactions.

• 出版日期2008-1
• 单位陕西师范大学