Deep desulfurization by oxidation using an active ionic liquid-supported Zr metal-organic framework as catalyst

作者：Wu, Jianxiang; Gao, Yilong; Zhang, Wei; Tan, Yueyue; Tang, Aomin; Men, Yong; Tang, Bohejin^*

来源：Applied Organometallic Chemistry, 2015, 29(2): 96-100.

DOI：10.1002/aoc.3251

• desulfurization
• metal-organic framework
• acidic catalyst
• oxidation catalysis

In this study, a Zrmetal-organic framework (UIO-66) was synthesized with zirconium tetrachloride and terephthalic acid using the solvent method. Then various masses of 1-methylimidazolium-3-propylsulfonate hydrosulfate (PSMIMHSO4) were supported on the UIO-66 as catalysts, which were used for catalytic oxidative desulfurization. Sulfur removal using 400mg of 40% PSMIMHSO4 supported on the UIO-66 of greater than 94% was obtained at 313 K for 20 min with an O/S molar ratio of 7:1. The results obtained in this work could provide useful information for the design of water-stable metal-organic frameworks with permanent porosity in applications of catalytic oxidative desulfurization.

• 出版日期2015-2
• 单位上海工程技术大学