Structural distortions of the spin-crossover material [Co(pyterpy)(2)](TCNQ)(2) mediated by supramolecular interactions

作者：Zhang, Xuan; Xie, Haomiao; Ballesteros-Rivas, Maria; Wang, Zhao-Xi; Dunbar, Kim R.^*

来源：Journal of Materials Chemistry C, 2015, 3(36): 9292-9298.

DOI：10.1039/c5tc01851j

• WIDE THERMAL HYSTERESIS
• MAGNETIC-PROPERTIES
• CRYSTAL-STRUCTURE
• COMPLEXES
• IRON(II)
• TRANSITION
• METAL
• TEMPERATURE
• LIGAND
• TCNQ(CENTER-DOT-)

The incorporation of TCNQ(center dot-) (7,7,8,8-tetracyanoquinodimethane) radicals as counterions for the spin-crossover material [Co(pyterpy)(2)](TCNQ)(2)center dot solvent (pyterpy = 4'-(4 '''-pyridyl)-2,2':6',2 ''-terpyridine) leads to structural distortions of the [Co(pyterpy)(2)](2+) spin-crossover cation as compared to [Co(pyterpy)(2)](PF6)(2). Variable temperature structural and magnetic studies indicate that the supramolecular p-stacking interactions between the terminal pyridyl groups and TCNQ radicals play a crucial role in the spin-crossover properties.

• 出版日期2015
• 单位上海大学