A comparative study of the structure and properties of Sn-modified lead zirconate titanate ferroelectric and antiferroelectric ceramics

作者：He Hui; Tan Xiaoli^*

来源：Journal of the American Ceramic Society, 2007, 90(7): 2090-2094.

DOI：10.1111/j.1551-2916.2007.01685.x

Comparative studies of the structure and property of a ferroelectric Pb0.99Nb0.02[(Zr0.57Sn0.43)(0.88)Ti-0.12](0.98)O-3 and an antiferroelectric Pb0.99Nb0.02[(Zr0.57Sn0.43)(0.94)Ti-0.06](0.98)O-3 ceramic were conducted. In addition to their different crystal structures, domain morphologies, Raman modes, and dielectric/ferroelectric properties, distinct fracture behaviors under Vickers indentation are also clearly seen. We propose that the antiferroelectric-to-ferroelectric phase transformation may have been triggered during the fracture process. Supporting evidence for localized phase transformation was provided by an in situ Raman spectroscopic experiment.

• 出版日期2007-7