An enantiopure pseudo-C-3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

作者:Axe Philip; Bull Steven D*; Davidson Matthew G; Jones Matthew D; Robinson Diane E J E; Mitchell William L; Warren John E
来源:Dalton Transactions, 2009, (46): 10169-10171.
DOI:10.1039/b918141p

摘要

A chiral pseudo-C-3-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.

  • 出版日期2009