A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide

作者：Czakler Matthias; Puchberger Michael; Artner Christine; Schubert Ulrich^*

来源：Monatshefte fur Chemie, 2014, 145(8): 1259-1262.

DOI：10.1007/s00706-014-1245-2

• Titanium alkoxides
• Carboxylate derivatives
• Coordination polymers
• Structure analysis

The coordination polymer [Ti(OiPr)(3)(OOCCH2CH2CH2C3N2H3)] (n) was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide. The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr)(3) groups through OR bridges was observed.

• 出版日期2014-8