mu(2)-Acetato-kappa O-2 : O '-tris(mu(2)-ferrocenecarboxylato-kappa O-2 : O ')bis[(N,N-dimethylformamide-kappa O)copper(II)]

作者：Luo Jian Hai; Huang Chang Cang^*; Huang Xi He; Wang Jin Gen

来源：Acta Crystallographica Section C-Crystal Structure Communications, 2008, 64: M121-M122.

DOI：10.1107/S0108270107044952

The title compound, [Cu2Fe3(C5H5)(3)(C2H3O2)(C6H4O2)(3)(C3H7NO)(2)], belongs to the classic dimeric paddle-wheel structure type. It is an unusual example in that it contains two different carboxylate groups, viz. ferrocenecarboxylate and acetate. With three ferrocenecarboxylate groups and only one acetate group bridging the two Cu centres, a noncentrosymmetric molecular arrangement results.

• 出版日期2008-3
• 单位福州大学