Highly active catalysts of bisphosphine oxides for asymmetric Heck reaction

作者:Hu Jian; Lu Yunpeng; Li Yongxin; Zhou Jianrong*
来源:Chemical communications, 2013, 49(82): 9425-9427.
DOI:10.1039/c3cc45233f

摘要

Bisphosphine oxides formed highly active asymmetric Heck catalysts, which were applied in asymmetric synthesis of pharmacologically active azacycles. Olefin insertion proceeded via cis pathways, different from P, N-ligands.

  • 出版日期2013