Atmospheric Mercury in the Barnett Shale Area, Texas: Implications for Emissions from Oil and Gas Processing

作者：Lan Xin^*; Talbot Robert; Laine Patrick; Torres Azucena; Lefer Barry; Flynn James

来源：Environmental Science & Technology, 2015, 49(17): 10692-10700.

DOI：10.1021/acs.est.5b02287

Atmospheric mercury emissions in the Barnett Shale area were studied by employing both stationary measurements and mobile laboratory surveys. Stationary measurements near the Engle Mountain Lake showed that thee median mixing ratio of total gaseous mercury (THg) was 138 ppqv (140 +/- 29 ppqv for mean +/- S.D.) during the June 2011 study period. A distinct diurnal variation pattern was observed in which the highest THg levels appeared near midnight, followed by a monotonic decrease until mid-afternoon. The influence of oil and gas (ONG) emissions was substantial in this area, as inferred from the i-pentane/n-pentane ratio (1.17). However, few THg plumes were captured by our mobile laboratory during a similar to 3700 km survey with detailed downwind measurements from 50 ONG facilities. One compressor station and one natural gas condensate processing facility were found to have significant THg emissions, with maximum THg levels of 963 and 392 ppqv, respectively, and the emissions rates were estimated to be 7.9 kg/-yr and 0.3 kg/-yr, respectively. Our results suggest that the majority of ONG facilities in this area are not significant sources of THg; however, it is highly likely that a small number of these facilities contribute a relatively large amount of emissions in the ONG sector.

• 出版日期2015-9-1