Near-infrared down-conversion in Pr3+-Yb3+ co-doped transparent glass ceramic containing Ca-5(PO4)(3)F nanocrystals

作者：Li, D. H.; Chen, Y. J.; Huang, J. H.; Gong, X. H.; Lin, Y. F.; Luo, Z. D.; Huang, Y. D.^*

来源：Physica B: Condensed Matter , 2014, 446: 12-16.

DOI：10.1016/j.physb.2014.04.010

• Pr3+-Yb3+ co-doped
• Transparent oxyfluoride glass ceramics
• Ca-5(PO4)(3)F nanouystals
• Down-conversion

Pr3+-Yb3+ co-doped transparent oxyfluoricle glass ceramics containing Ca-5(PO4)(3)F nanocrystals were synthesized by a melting-quenching method. Spectral analyses demonstrate that Pr3+ and Yb3+ ions are both incorporated into the Ca-5(PO4)(3)F nanocrystals. Near-infrared down-conversion around 1000 nm was observed when the glass ceramics were excited at 435 nm. The maximum actual down-conversion efficiency for 0.3 mol% Pr3+-0.8 mol% Yb3+ co-doped glass ceramic is about 125%.

• 出版日期2014-8-1
• 单位中国科学院大学; 中国科学院福建物质结构研究所