摘要

The two dimensional Mn-II coordination polymer [Mn-3(pic)(2)(N-3)(4)(CH3OH)](n) (1) with the ligands azide and picolinic acid (Hpic) was synthesized and characterized by IR spectroscopy, elemental analysis, and powder and single-crystal X-ray diffraction analysis. Meanwhile, analysis of the magnetic properties revealed antiferromagnetic exchange for polymer 1.