A multifunctional device to determine specific volume, thermal conductivity and crystallization kinetics of semi-crystalline polymers

作者：Tardif Xavier; Agazzi Alban; Sobotka Vincent^*; Boyard Nicolas; Jarny Yvon; Delaunay Didier

来源：Polymer Testing, 2012, 31(6): 819-827.

DOI：10.1016/j.polymertesting.2012.05.008

• Heat transfer
• Thermal conductivity
• Crystallization kinetics
• Specific volume
• PvTx

The control and optimization of heat transfer during the forming of thermoplastic parts is of primary importance since they impact on the quality of final parts. The modelling of this transfer requires accurate knowledge of the polymer thermo-physical properties, and also of the parameters describing the crystallization, this latter data being very sensitive to the thermal history for semi-crystalline polymers. The experimental determination of these parameters requires the use of many instruments, which is time consuming. To address this issue, a home-built instrumented mould was designed to measure and identify several properties from a single experiment. Specific volume, transverse thermal conductivity in amorphous and solid states can be estimated as a function of the temperature. Parameters of a crystallization kinetics model are identified with a non invasive procedure. Our methodology is illustrated on a well-known semi-crystalline thermoplastic. Identified parameters are compared with literature results.

• 出版日期2012-9