Phase stability of some actinides with brannerite structure at high pressures

作者：Zhang F X; Lang M; Liu Zhenxian; Ewing R C^*

来源：Journal of Solid State Chemistry, 2011, 184(11): 2834-2839.

DOI：10.1016/j.jssc.2011.08.022

• Brannerite
• Actinide
• High pressure
• Amorphization

Structure behavior of actinide brannerites ThTi(2)O(6), Y(0.5)U(0.6)Ti(1.5)Nb(0.5)O(6) and their analog oxide CeTi(2)O(6) was studied at high pressure by using in situ x-ray diffraction, Raman scattering and infra-red absorption techniques, respectively. Brannerite structure was found to be not stable and started to become amorphous at pressures above 20 GPa. Some minor crystalline phase(s) due to phase decomposition was observed in all the three samples during pressurization. In addition, the observed bulk modulus indicated that the actinide-bearing brannerites are more compressible than their analog compound CeTi(2)O(6), which may be related to the asymmetric 5f electron orbits of actinide elements.

• 出版日期2011-11