A hydroboration route to geminal P/B frustrated Lewis pairs with a bulky secondary phosphane component and their reaction with carbon dioxide

作者:Jian Zhongbao; Kehr Gerald; Daniliuc Constantin G; Wibbeling Birgit; Erker Gerhard
来源:Dalton Transactions, 2017, 46(35): 11715-11721.
DOI:10.1039/c7dt02315d

摘要

The hydroboration of a secondary alkynyl phosphane gives a geminal P/B frustrated Lewis pair that reacts with carbon dioxide.

  • 出版日期2017-9-21