Development of an Analytical Method Based on Temperature Controlled Solid-Liquid Extraction Using an Ionic Liquid as Solid Solvent

作者：Pan, Zhongwei^*; Wang, Zhengquan; Zhu, Linna; Zhu, Zhiming; Cai, Jinying; Shen, Xiaoman; Fan, Tingli; Zhang, Yingnan; Chen, Zhixiu

来源：Molecules, 2015, 20(12): 22137-22145.

DOI：10.3390/molecules201219842

• determination of Fe2+
• tea
• temperature controlling solid-liquid separation
• ionic liquid as solid solvent

At the present paper, an analytical method based on temperature controlled solid-liquid extraction (TC-SLE) utilizing a synthesized ionic liquid, (N-butylpyridinium hexafluorophosphate, [BPy]PF6), as solid solvent and phenanthroline (PT) as an extractant was developed to determine micro levels of Fe2+ in tea by PT spectrophotometry. TC-SLE was carried out in two continuous steps: Fe2+ can be completely extracted by PT-[BPy]PF6 or back-extracted at 80 degrees C and the two phases were separated automatically by cooling to room temperature. Fe2+, after back-extraction, needs 2 mol/L HNO3 as stripping agent and the whole process was determined by PT spectrophotometry at room temperature. The extracted species was neutral Fe(PT)(m)Cl-2 (m = 1) according to slope analysis in the Fe2+-[BPy]PF6-PT TC-SLE system. The calibration curve was Y = 0.20856X - 0.000775 (correlation coefficient = 0.99991). The linear calibration range was 0.10-4.50 g/mL and the limit of detection for Fe2+ is 7.0 x 10(-2) g/mL. In this method, the contents of Fe2+ in Tieguanyin tea were determined with RSDs (n = 5) 3.05% and recoveries in range of 90.6%-108.6%.

• 出版日期2015-12
• 单位泉州师范学院