Adsorption Isotherms, Kinetics, and Desorption of 1,2-Dichloroethane on Chromium-Based Metal Organic Framework MIL-101

作者：Xian, Shikai; Li, Xiaolin; Xu, Feng; Xia, Qibin; Li, Zhong^*

来源：Separation Science and Technology (Philadelphia), 2013, 48(10): 1479-1489.

DOI：10.1080/01496395.2012.738756

• 1
• 2-dichloroethane adsorption isotherm
• desorption activation energy
• diffusion coefficients
• isosteric heat of adsorption
• metal-organic frameworks MIL-101

Adsorption equilibrium and kinetics of 1,2-dichloroethane on a chromium-based metal-organic framework MIL-101 were studied. Desorption activation energies of 1,2-dichloroethane on the MIL-101 were measured using temperature program desorption (TPD) experiments. Results showed that the adsorption capacity of the MIL-101 for 1,2-dichloroethane is 19mmol/g at 288K, being much higher than those of some activated carbon, zeolite, and MWCNTs. The isotherms of 1,2-dichloroethane were well fitted by the Langmuir equation. The isosteric heat and diffusion coefficients of 1,2-dichloroethane adsorption on the MIL-101 were separately within the range of 42.061.6kJ/mol and range of 0.8542.246x10(10)cm(2)/s. TPD spectra exhibited two types of adsorption sites on the MIL-101 with desorption activation energy of 48.6 and 87.6kJ/mol separately. Multiple recycle runs of 1,2-dichloroethane adsorption-desorption at 298K (10mbar for adsorption and 0.05mbar for desorption) showed the 1,2-dichloroethane adsorption on the MIL-101 is highly reversible, and desorption efficiency is up to 98.42%.

• 出版日期2013-5-1
• 单位华南理工大学