Phenolic resin as a carbon source for the synthesis of monometallic Mo and bimetallic CoMo carbides via carbothermal reduction route

作者：Gao, Liang; Shi, Yan; Yao, Zhiwei^*; Gao, Haifeng; Sun, Yue; liang, Feixue; Jiang, Baojiang^*

来源：Phosphorus, Sulfur, and Silicon and the Related Elements, 2018, 193(5): 267-272.

DOI：10.1080/10426507.2017.1418740

• Phenolic resin
• nanostructured carbides
• carbothermal reduction
• monometallic Mo carbide
• bimetallic CoMo carbide

It was the first time that phenolic resin (PR) was used as a carbon source for the synthesis of nanostructured monometallic Mo and bimetallic CoMo carbides via carbothermal reduction route. The results showed that phase-pure -Mo2C can be formed under an Ar atmosphere at 900 degrees C or a H-2 atmosphere above 700 degrees C. However, almost pure CoMo carbides (Co3Mo3C and Co6Mo6C) can be obtained only under a H-2 atmosphere at a low temperature of 630 degrees C for 24 and 48h, respectively. The role of PR in the preparation process has been investigated and a detailed formation mechanism was proposed based on the experimental results. @@@ [GRAPHICS]

• 出版日期2018
• 单位黑龙江大学; 辽宁石油化工大学