A Simple Synthesis of Two-Dimensional Ultrathin Nickel Cobaltite Nanosheets for Electrochemical Lithium Storage

作者：Zhu Youqi; Cao Chuanbao^*

来源：Electrochimica Acta, 2015, 176: 141-148.

DOI：10.1016/j.electacta.2015.06.130

• nickel cobaltite
• nanosheet
• anode
• lithium ion battery

We report a simple microwave-assisted method to fabricate high-quality two-dimensional (2D) ultrathin NiCo2O4 nanosheets with a geometrically graphene-like architecture. The unique large-area nanostructures represent an ultrahigh surface atomic ratio with almost all active elements exposed outside for surface-dependent electrochemical reaction processes. Experimental results reveal that the as-synthesized ultrathin NiCo2O4 nanosheets show excellent electrochemical performances for lithium storage application. The ultrathin NiCo2O4 nanosheets could deliver a high first discharge capacity (1287.1 mAh g(-1)) with initial Coulombic efficiency of 80.0% at 200 mA g(-1) current density. The reversible lithium storage capacity still retains at 804.8 mAh g(-1) in the 100th cycle, suggesting a good cycling stability. The excellent electrochemical properties of the as-synthesized NiCo2O4 nanosheets could be ascribed to the unique ultrathin 2D architecture, which could offer large exposed active surface with more lithium-insertion channels and significantly reduce lithium ion diffusion distance. The cost-efficient synthesis and excellent lithium storage properties make the 2D NiCo2O4 nanosheets as a promising anode material for high-performance lithium ion batteries.

• 出版日期2015-9-10
• 单位北京理工大学