Nanofoaming to Boost the Electrochemical Performance of Ni@Ni(OH)2 Nanowires for Ultrahigh Volumetric Supercapacitors

作者：Xu, Shusheng; Li, Xiaolin; Yang, Zhi^*; Wang, Tao; Jiang, Wenkai; Yang, Chao; Wang, Shuai; Hu, Nantao; Wei, Hao; Zhang, Yafei

来源：ACS Applied Materials & Interfaces, 2016, 8(41): 27868-27876.

DOI：10.1021/acsami.6b10700

• nanofoaming
• nickel nanowire
• supercapacitor
• volumetric capacity
• energy storage

Three-dimensional free-standing film electrodes have aroused great interest for energy storage devices. However, small volumetric capacity and low operating voltage limit their practical application for large energy storage applications. Herein, a facile and novel nanofoaming process was demonstrated to boost the volumetric electrochemical capacitance of the devices via activation of Ni nanowires to form ultrathin nanosheets and porous nanostructures. The as-designed free-standing Ni@Ni(OH)(2) film electrodes display a significantly enhanced volumetric capacity (462 C/cm(3) at 0.5 A/cm(3)) and excellent cycle stability. Moreover, the as developed hybrid supercapacitor employed Ni@Ni(OH)(2) film as positive electrode and graphene-carbon nanotube film as negative electrode exhibits a high volumetric capacitance of 95 F/cm(3) (at 0.25 A/cm(3)) and excellent cycle performance (only 14% capacitance reduction for 4500 cycles). Furthermore, the volumetric energy density can reach 33.9 mWh/cm(3), which is much higher than that of most thin fihn lithium batteries (1-10 mWh/cm(3)). This work gives an insight for designing high-volume three-dimensional electrodes and paves a new way to construct binder-free film electrode for high-performance hybrid supercapacitor applications.

• 出版日期2016-10-19
• 单位上海交通大学