A novel nonanuclear Cu-II carboxylate-bridged cluster aggregate with an S=7/2 ground spin state

作者：Murugesu M; King P; Clerac R; Anson CE; Powell AK^*

来源：Chemical Communications, 2004, (6): 740-741.

DOI：10.1039/b316233h

The Cu-II aggregate in [Cu-9(cpida)(6)(MeOH)(6)].6(MeOH) (H(3)cpida = 2-(carboxyphenyl)iminodiacetic acid I is made up of two weakly ferromagnetically coupled carboxylate-bridged Cu-4 units that are antiferromagnetically linked through a central Cu-II to give a Cu-9 core with an S = 7/2 spin ground state.

• 出版日期2004-3-21