Amino acid functionalized metal-organic frameworks by a soft coupling-deprotection sequence

作者:Canivet Jerome*; Aguado Sonia; Bergeret Gerard; Farrusseng David
来源:Chemical communications, 2011, 47(42): 11650-11652.
DOI:10.1039/c1cc15541e

摘要

Covalent post-synthetic modification of a MOF, (In) MIL-68-NH(2), is carried out in a novel fashion to immobilize amino acids within the structure. Solid-phase peptide coupling methodology opens new perspectives for anchoring chiral bio- and catalytically active species. This could facilitate the immobilization of highly active and/or coordinating moieties inside MOF cavities.

  • 出版日期2011