A chimeric design of heterospin 2p-3d, 2p-4f, and 2p-3d-4f complexes using a novel family of paramagnetic dissymmetric compartmental ligands

作者:Patrascu Andrei A; Calancea Sergiu; Briganti Matteo; Soriano Stephane; Madalan Augustin M; Allao Cassaro Rafael A; Caneschi Andrea; Totti Federico*; Vaz Maria G F*; Andruh Marius*
来源:Chemical communications, 2017, 53(48): 6504-6507.
DOI:10.1039/c7cc03236f

摘要

End-off bicompartmental ligands bearing a nitronyl-nitroxide arm have been designed for synthesizing various heterospin molecular systems. These ligands can selectively interact with 3d and 4f metal ions, leading to 2p-4f, 2p-3d, and 2p-3d-4f complexes. The magnetic properties of the 2p-4f and 2p-3d-4f complexes have been investigated and rationalized by theoretical calculations.

  • 出版日期2017-6-18