An unprecedented bridging [Ag-2(NO3)(6)](4-) anion as a component of an infinite silver(I) molecular ladder incorporating a dinuclear cationic silver complex of a bis-dipyridylamine ligand

作者：Antonioli Bianca; Clegg Jack K; Bray David J; Gloe Kerstin; Gloe Karsten; Hesske Holger; Lindoy Leonard F

来源：CrystEngComm, 2006, 8(10): 748-750.

DOI：10.1039/b611270f

The interaction of silver( I) nitrate with the polypyridyl ligand (I) formed from two dipyridylamine units joined at their secondary amines by a 2,6-lutidinyl bridge results in a molecular ladder motif that consists of pairs of cationic [Ag-2(L) MeCN](2+) units bridged by an unprecedented [Ag-2(NO3) (6)](4-) anion.

• 出版日期2006