Process simulations of HI decomposition via reactive distillation in the sulfur-iodine cycle for hydrogen manufacture

作者：Murphy James E; O'Connell John P^*

来源：International Journal of Hydrogen Energy, 2012, 37(5): 4002-4011.

DOI：10.1016/j.ijhydene.2011.11.108

• Hydrogen production
• Sulfur-iodine process
• Thermochemical decomposition of water
• Reactive distillation of polyhydriodic acid
• Process simulation

Process simulations of HI decomposition via reactive distillation in the Sulfur-Iodine (S-I) cycle have been performed using heat pumps for energy recovery and a recently developed thermodynamic properties model. Several differences from previous flow sheets have been found through manual optimization of reflux ratio, number of stripping and rectifying stages, and pressure of the distillation column for typical inlet conditions to the HIx Section III. In particular, the RD column should have a minimal stripping section, can have as few as 10 total stages, an operating pressure of 12 bar, and a reflux ratio of 0.75, while achieving the production requirements. Though this design has limited improvement in energy requirements because the General Atomics energy recovery system is extremely effective, these results mean there should be a significant reduction in capital costs from prior estimates. In addition, as the inlet flow rate is increased, the input energy requirements decrease because of an increased ratio of H2O to I-2 in the reboiler, lowering its temperature, and reducing the temperature differences for heat pump operations. The optimal inlet flow is between 126 and 140 mol/mol H-2, with a Section energy requirement of 367 kJ/mol H-2, and an overall process thermal efficiency estimated to be 41.5% relative to the higher heating value of hydrogen. These findings suggest there may be greater flexibility in conditions for the Bunsen reaction section as well as other possibilities for further energy efficiency improvement.

• 出版日期2012-3