A novel anode material derived from organic-coated ZIF-8 nanocomposites with high performance in lithium ion batteries

作者:Han, Yuzhen; Qi, Pengfei; Li, Siwu; Feng, Xiao; Zhou, Junwen; Li, Haiwei; Su, Shuangyue; Li, Xingguo; Wang, Bo*
来源:Chemical communications, 2014, 50(59): 8057-8060.
DOI:10.1039/c4cc02691h

摘要

A general method of preparing nanocomposites from a metal-organic framework coated with hydroxyl, pyrrolyl and/or carboxyl functionalized organics is introduced. Pyrolysis of these nanocomposites gives anode materials with improved discharge capacity (750 mA h g(-1)) and cyclability. They also show enhanced Coulombic efficiency over the initial 5-10 cycles and decreased internal impedance.