A New "Opened-Cube" (H2O)(10) Cluster and Undulated Water Chain in Porous Metal-Organic Frameworks

作者:Wang Li Yan; Yang Yuan; Liu Kui; Li Bao Long*; Zhang Yong
来源:Crystal Growth & Design, 2008, 8(11): 3902-3904.
DOI:10.1021/cg800484k

摘要

A novel three-dimensional coordination polymer [Cd-2(btec)(btb)(3)](H2O)(10) (1) (btb = 1,4-bis(1,2,4-triazol-1-yl)butane; btec = 1,2,4,5-benzenetetracarboxylate) containing an "opened-cube" with an outer edge discrete water decamer and a thick two-dimensional network [Cd-2(phth)(2)(btb)(H2O)(3)](H2O)(4.5) (2) (phth = 1,2-benzenedicarboxylate) containing an undulated water chain have been synthesized and characterized by single crystal X-ray diffraction analysis.