科研之友
微信
新浪微博
Facebook
分享链接
摘要
Acid treatment of densely substituted 2-silyl-1,2-dihydropyridines provides a new and convenient entry to reactive azomethine ylides that can (1) be protonated and reduced with high stereoselectivity to give piperidines, (2) participate in [3 + 2] dipolar cycloaddition to give tropanes, and (3) undergo a Nazarov-like 6-pi electrocyclization that upon reduction give 2-azabicyclo[3.1.0] systems.
- 出版日期2013-2-20
