An Environmentally Friendly Nb-P-Si Solid Catalyst for Acid-Demanding Reactions

作者：Aronne Antonio^*; Di Serio Martino; Vitiello Rosa; Clayden Nigel J; Minieri Luciana; Imparato Claudio; Piccolo Alessandro; Pernice Pasquale; Carniti Paolo; Gervasini Antonella^*

来源：Journal of Physical Chemistry C, 2017, 121(32): 17378-17389.

DOI：10.1021/acs.jpcc.7b05886

Here, we report the structural characteristics, the surface properties, and the catalytic performances of a Nb-P-Si ternary oxide material (2.5Nb(2)O(5).2.5P(2)O(5).95SiO(2), 2.5NbP) in two reactions of importance for biomass valorisation and green industrial production: hydrolysis of inulin and esterification of oleic acid with, polyalcohol for biolubricant production. High dispersion of the Nb centers, ascertained by UV-vis-DRS, Si-29, P-31, and H-1 solid-state NMR spectroscopy, is the key point for the successful activity of 2.5NbP. Intrinsic and effective acidities of the sample were studied by FT-IR of adsorbed pyridine in the absence and presence of water and by volumetric titrations of the acid sites in cydohexane and in water, to enlighten the nature and amount of acid sites in different environments. For both studied reactions, 2.5NbP catalyst exhibits water-tolerant acidic sites, mainly Bronsted ones, giving higher activity and better stability in the reaction medium than well-known niobium oxophosphate catalyst, which is considered one of the best water-tolerant acid catalysts.

• 出版日期2017-8-17