High-resolution and sensitivity through-bond correlations in ultra-fast magic angle spinning (MAS) solid-state NMR

作者：Bertini Ivano; Emsley Lyndon; Felli Isabella C; Laage Segolene; Lesage Anne^*; Lewandowski Jozef R; Marchetti Alessandro; Pierattelli Roberta; Pintacuda Guido

来源：Chemical Science, 2011, 2(2): 345-348.

DOI：10.1039/c0sc00397b

We introduce a new experiment, which makes use of Spin State Selective manipulations to perform sensitive and resolved through-bond correlations in organic and biological solids at high-fields and under ultra-fast MAS. The scheme is the shortest and most sensitive through-bond correlation method introduced so far in solids, yields resolved fingerprints of uniformly (13)C-labeled biomolecules, and constitutes a tool to highlight slight static structural disorder around crystallographically equivalent molecules in microcrystalline samples.

• 出版日期2011