Annealing effect in bulk heterojunction organic solar cells utilizing liquid crystalline phthalocyanine

作者:Ohmori Masashi*; Fukui Hitoshi; Quang Duy Dao; Kumada Taishi; Fujii Akihiko; Shimizu Yo; Ozaki Masanori
来源:Japanese Journal of Applied Physics, 2014, 53(5): 05FZ02.
DOI:10.7567/JJAP.53.05FZ02

摘要

The effect of annealing on bulk heterojunction solar cells utilizing the liquid crystalline phthalocyanine, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH(2)), fabricated using various solvents was studied. In the solar cells fabricated using chloroform, the power conversion efficiency was enhanced from 1.2 to 2.5% by thermal annealing at 75 degrees C, near the glass-transition temperature of the bulk heterojunction film. We discuss the effects of annealing on the photovoltaic properties by considering the exciton dissociation and carrier transport efficiencies obtained from photoluminescence spectra, X-ray diffraction measurement, and atomic force microscope observation.

  • 出版日期2014-5