HAP-Pd(0): A HIGHLY EFFICIENT RECYCLABLE HETEROGENEOUS CATALYST FOR THE SELECTIVE REDUCTION OF CARBON-CARBON DOUBLE BOND IN alpha,beta-UNSATURATED KETONES

作者：Chambyal Omkar Singh; Paul Satya^*; Shamim Tahira; Gupta Monika; Gupta Rajive; Loupy Andre

来源：Synthetic Communications, 2013, 43(5): 656-667.

DOI：10.1080/00397911.2011.605242

• HAP-Pd(0)
• heterogeneous catalysis
• reductions
• selectivity
• alpha,beta-unsaturated ketones

A recyclable heterogeneous hydroxyapatite-supported palladium(0) catalyst was prepared by a simple procedure and successfully applied for the selective reduction of carbon-carbon double bond in alpha,beta-unsaturated ketones using HCOONH4 as hydrogen transfer agent. The workup procedure is simple, and the catalyst could be recovered by simple filtration and recycled for five consecutive runs without significant loss of activity.

• 出版日期2013