A (3,6)-connected layer with an unprecedented adeninate nucleobase-derived heptanuclear disc

作者:Liu Zheng Yu; Zhang Hong Yun; Yang En Cui*; Liu Zhong Yi; Zhao Xiao Jun
来源:Dalton Transactions, 2015, 44(12): 5280-5283.
DOI:10.1039/c4dt04020a

摘要

A (3,6)-connected layer with an adeninate nucleobase-derived Cu-7(II) disc was reported, in which six spin-parallel Cu-II ions in the exterior of the disc are antiferromagnetically coupled with the central one to give an S = 5/2 ground-state.