A new organic-inorganic hybrid material based on a preformed chalcogenide building block and lanthanide

作者：Duval Sylvain; Dumur Frederic; Marrot Jerome; Simonnet Jegat Corine^*; Cadot Emmanuel

来源：Inorganic Chemistry Communications, 2012, 18: 11-14.

DOI：10.1016/j.inoche.2011.12.043

• Molybdenum
• Chalcogenide complexes
• Metal-organic materials
• Lanthane
• Hydrothermal synthesis

Chalcogenide cluster [Mo3S4(HNTA)(3)](2-) was used as precursor to generate new organic-inorganic hybrid material. La2Cl[Mo3S4(NTA)(3)]center dot 17H(2)O (1) was obtained by hydrothermal synthesis starting from [Mo3S4 (NTA)(3)](5-) and La3+ cation. Compound (1) was fully characterised by XRD, FTIR, TGA and elemental analysis. (1) crystallises in the P-1 space group with a = 11.2219(3)angstrom, b = 13.2435(3)angstrom, c = 17.6351(5)angstrom, alpha = 82,365(1)degrees, beta=72,787(1)degrees, gamma=68,608 (1)degrees, V = 2330.11(11) angstrom(3) and Z = 2. Single-crystal X-ray diffraction analyses evidenced that the resulting 3D network consists of [Mo3S4(NTA)(3)](5-) units connected through La3+ cations.

• 出版日期2012-4