A new type of photomagnetic system: photoinduced charge transfer in polyoxometalate-based organic-inorganic hybrid

作者：Gao, Qiao; Li, Fengyan^*; Sun, Zhixia; Xu, Lin^*; Sun, Minghui

来源：Dalton Transactions, 2016, 45(6): 2422-2425.

DOI：10.1039/c5dt03748d

• SPIN-CROSSOVER
• MAGNETIC-PROPERTIES
• HETEROPOLY BLUES
• COORDINATION
• ELECTRONS
• LIGHT
• ELECTROCHROMISM
• COMPLEXES
• VANADIUM
• CRYSTAL

Herein, we show a new photomagnetic system that gives rise to the magnetic transformation from diamagnetism to paramagnetism by photoinduced intramolecular charge transfer in the polyoxometalate-based organic-inorganic hybrid, [(VMo6O22)(2){O2C(CH2)(2)CO2}(3)] (1).

• 出版日期2016
• 单位东北师范大学