Novel two-dimensional Co(II) and Cd(II) coordination polymers with intriguing net topologies

作者：Lee Jhen Yi; Lee Jing Yi; Lee Hon Man^*

来源：Inorganic Chemistry Communications, 2015, 52: 16-19.

DOI：10.1016/j.inoche.2014.12.003

• Crystal structure
• 2,6-Bis(imidazole-1-yl)pyridine
• Cadmium
• Cobalt
• Net topology

Three new two-dimensional coordination polymers were constructed from 2,6-bis(imidazole-1-yl)pyridine (2.6-bip), terephthalic acid (1,4-bdcH(2)), and M(NO3)center dot nH(2)O (M = Co, Cd). [M(2,6-bip)(1,4-bdc)] (1: M = Co; 2: M = Cd) were prepared under hydrothermal condition, whereas [Cd(2,6-bip)(1,4-bdc)center dot xDMF] (3) was obtained under solvothermal condition in DMF solvent. Single-crystal X-ray analyses revealed the first example of a 2D 4-connected net of 6(6) topology in 1 and 2 and a rare 2D 4,5-connected net of 4,5 L20 topology in 3. All these complexes were thermally robust and emissive in solid-states. This work confirmed the versatility of using hingelike 2,6-bip as a linker and the importance of solvent effect in the process of framework formation.

• 出版日期2015-2